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Journal Articles

No secondary waste recycle technology for rare metals using the hydrophilic extraction with phase transfer phenomena

Tsukahara, Takehiko*; Saga, Kaname*; Suzuki, Hideya*; Matsumura, Tatsuro

Kurin Tekunoroji, 29(12), p.4 - 7, 2019/12

no abstracts in English

Journal Articles

Effect of heavy ion irradiation on optical property of radiation-crosslinked hydroxypropyl cellulose gel containing methacrylate monomers

Hiroki, Akihiro; Yamashita, Shinichi*; Kimura, Atsushi; Nagasawa, Naotsugu; Taguchi, Mitsumasa

Nuclear Instruments and Methods in Physics Research B, 365(Part B), p.583 - 586, 2015/12

Effects of liner energy transfer (LET) and dose rate on the optical property of polymer gel dosimeters were investigated. The dosimeter prepared by using a radiation-crosslinked hydroxypropyl cellulose gel and methacrylate monomers such as 2-hydroxyethyl methacrylate and nonaethylene glycol dimethacrylate showed the color change from colorless to white with the He, C, Fe ions irradiation. Absorbance of the irradiated dosimeters increased with the dose up to 10 Gy. The absorbance of the dosimeters at the same total dose decreased with increasing dose rate in the range of 0.1 to 6.8 Gy/min. The absorbance decreased in order of He, C, Fe ions, which was in agreement with a change of LET. The increase in LET affected the decrease in the number of polymerization initiator such as OH radical and hydrated electron, resulting in the reduction of the absorbance of the dosimeters.

Journal Articles

Enhancement in dose sensitivity of polymer gel dosimeters composed of radiation-crosslinked gel matrix and less toxic monomers

Hiroki, Akihiro; Yamashita, Shinichi*; Taguchi, Mitsumasa

Journal of Physics; Conference Series, 573(1), p.012028_1 - 012028_4, 2015/01

BB2014-0610.pdf:0.75MB

 Times Cited Count:4 Percentile:79.08(Engineering, Biomedical)

Polymer gel dosimeters based on radiation-crosslinked hydroxypropyl cellulose gel were prepared, which comprised 2-hydroxyethyl methacrylate (HEMA) and polyethylene glycol dimethacrylate (9G) as less toxic monomers and tetrakis (hydroxymethyl) phosphoniumu chloride (THPC) as an antioxidant. The dosimeters exposed to $$^{60}$$Co $$gamma$$-rays became cloudy at only 1 Gy. The irradiated dosimeters were optically analyzed by using a UV-vis spectrophotometer to evaluate dose response. Absorbance of the dosimeters linearly increased in the dose range from 0 to 10 Gy. The dose sensitivity increased with increasing 9G concentration. The dosimeter with 2 wt% HEMA, 3 wt% 9G, and 0.16 wt% THPC exhibited about 0.04 Abs Gy$$^{-1}$$ of the dose sensitivity. The dose sensitivity of the dosimeters was also enhanced by increment in THPC, reached about 0.06 Abs Gy$$^{-1}$$ at 0.40 wt% THPC.

Journal Articles

Thermoresponsive conductivity of poly(${it N}$-isopropylacrylamide)/potassium chloride gel electrolytes

Chen, J.; Maekawa, Yasunari; Yoshida, Masaru; Tsubokawa, Norio*

Journal of Polymer Science, Part B; Polymer Physics, 40, p.134 - 141, 2001/11

 Times Cited Count:7 Percentile:27.52(Polymer Science)

no abstracts in English

Journal Articles

Thermo-responsive behavior of a methacryloyl-DL-alanine methyl ester polymer gel prepared by radiation-induced polymerization

Z-L.Ding*; Yoshida, Masaru; Asano, Masaharu; Z-T.Ma*; Omichi, Hideki; Katakai, Ryoichi*

Radiation Physics and Chemistry, 44(3), p.263 - 272, 1994/00

 Times Cited Count:13 Percentile:73.36(Chemistry, Physical)

no abstracts in English

Journal Articles

Artificially intelligent hydrogels responding to external stimuli such as temperature and pH

Yoshida, Masaru; J.S.Yang*; Kumakura, Minoru*; Hagiwara, Miyuki; Katakai, Ryoichi*

European Polymer Journal, 27(9), p.997 - 1005, 1991/00

 Times Cited Count:35 Percentile:81.25(Polymer Science)

no abstracts in English

Oral presentation

Dose response of polymer gel dosimeter based on hydroxypropyl cellulose hydrogel; Toward the application on heavy ion therapy

Hiroki, Akihiro; Yamashita, Shinichi*; Kimura, Atsushi; Nagasawa, Naotsugu; Taguchi, Mitsumasa

no journal, , 

The polymer gel dosimeters consisting of 2-hydroxyethyl methacrylate, nonaethylene glycol dimethacrylate, and tetrakis (hydroxymethyl) phosphoniumu chloride with radiation-crosslinked hydroxypropyl cellulose gel were irradiated with 290 MeV/u C ions at HIMAC. Absorbance of the irradiated dosimeters at 660 nm increased with an increase in the dose up to 10 Gy. The dose response of the dosimeter irradiated with C ions was about 0.007 Abs. Gy$$^{-1}$$, which decreased in about one-tenth of the $$gamma$$-irradiated sample. RGB value of the image obtained by using a flat-bed image scanner also increased with increasing dose. Distribution of the dose estimated from RGB value of the scanned image was almost agreement with that of a general radiochromic film for the radiotherapy.

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